S as function of V and T. For simplicity, we consider first a pure phase component i. Integration of (91) yields
(107)
Expansion in an ideal gas and a deviation term:
(108)
Solving the last integral in (108):
(109)
Extending the lower integration limit:
(110)
The first two terms of (110) are the S of an pure hypothetical ideal gas. If the system is a mixture ideal mixing entropy has to be added
(111)
Notice
This website processes personal data (e.g. browsing data or IP addresses) and use cookies or other identifiers, which are necessary for its functioning and required to achieve the purposes illustrated in the cookie policy.
You accept the use of cookies or other identifiers by closing or dismissing this notice, by clicking a link or button or by continuing to browse otherwise.
This site is GPDR compliant.
Privacy policy: no personal data and no comments are collected. No data are collected for statistical purposes.